Real Name: unknown
Appeared in:
Season 3: Dr. Strange, Venom Returns, Carnage
Voiced by: Tony Jay
Big Wheel
Real Name: unknown
Appeared in:
Season 3: Rocket Racer
Voiced by: Michael Des Barnes
Calypso
Real Name: Dr. Mariah Crawford
Appeared in:
Season 4: The Return of Kraven
Voiced by: Susan Beaubian
Carnage
Real Name: Cletus Kassidy
Appeared in:
Season 3: Venom Returns, Carnage
Voiced by: Scott Cleverdon
Chameleon
Real Name: Dimitri Smerdyakov
Appeared in:
Season 1: Day of the Chameleon
Season 2: The Insidious Six, Battle of the Insidious Six
Season 3: Framed, The Man Without Fear
Season 4: The Cat, The Black Cat
Season 5: The Six Forgotten Warriors 5 parter
Voiced by: No one (he would morph into someone and then talk, although Jim
Cummings did provide his grunts)
Doctor Octopus
Real Name: Dr. Otto Octavius
Appeared in:
Season 1: Doctor Octopus, Armed and Dangerous,
Season 2: The Insidious Six, Battle of the Insidious Six
Season 3: Make a Wish, Attack of the Octobot
Season 4: The Cat, The Black Cat
Season 5: The Six Forgotten Warriors 5 parter, Gauntlet of Red Skull
Voiced by: Efrem Zimbalist Jr.
Dormammu
Real Name: Dormammu
Appeared in:
Season 3: Dr. Strange, Venom Returns, Carnage
Voiced by: Ed Gilbert
Doctor Doom
Real Name: Victor Von Doom
Appeared in:
Season 5: Doom
Voiced by: Thomas Kane
Electro
Real Name: Rhienholdt Kragov
Appeared in:
Season 5: The Six Forgotten Warriors 5 parter
Voiced by: Phil Proctor
Green Goblin 1
Real Name: Norman Osborn
Appeared in:
Season 3: Enter the Green Goblin, Goblin War, Turning Point
Season 4: Return of the Green Goblin
Season 5: The Wedding, I Really, Really Hate Clones
Voiced by: Neil Ross
Green Goblin 2
Real Name: Harry Osborn
Appeared in:
Season 4: Return of the Green Goblin
Season 5: The Wedding
Voiced by: Gary Imhoff
Hammerhead
Real Name: unknown
Appeared in:
Season 2: Insidious Six, Battle of Insidious Six, Tablet of Time, Ravages of Time
Voiced by: Nicky Blair
Herbert Landon
Real Name: Herbert Landon
Appeared in:
Too many episodes to count
Voiced by: David Warner
The Hobgoblin
Real Name: Jason Phillip Macendale
Appeared in:
Season 1: The Hobgoblin Parts 1 and 2
Season 2: The Mutant Agenda, Mutant's Revenge
Season 3: Rocket Racer (as Jason), The Spot, Goblin War
Season 5: I Really, Really Hate Clones
Voiced by: Mark Hamill
Hydro-Man
Real Name: Morrie Bench
Appeared in:
Season 2: Hydro-Man
Season 5: Return of Hydro-Man parts 1 and 2
Voiced by: Rob Paulsen
Iceberg
Real Name: unknown
Appeared in:
Season 4: The Prowler
Voiced by: Lawrence A. Mandley
J. Jonah Jameson
Real Name: J. Jonah Jameson
Appeared in:
Too many episodes to count
Voiced by: Ed Asner
The Kingpin
Real Name: Wilson Fisk
Appeared in:
Too many episodes to count
Voiced by: Roscoe Lee Browne
Kraven the Hunter
Real Name: Sergei Kravinoff
Appeared in:
Season 1: Kraven the Hunter
Season 2: Duel of the Hunters
Season 4: The Return of Kraven
Voiced by: Gregg Berger
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Featuring Spider-Man, X-Men, Fantastic Four, Iron Man, Incredible Hulk, and the Silver Surfer.