This episode is available on the "Spider-Man: The Ultimate Villain Showdown" VHS/DVD, which you can buy from the BUY SPIDER-MAN STUFF section of this site.
This is the first episode to explain Spider-Man's origin in detail (since plans for James Cameron's movie had been scrapped).
The riot scene when Dr. Octopus attacks
Michael Pingree features clips from the upcoming episode
(when Venom attacks Stark Enterprises). I guess
was finished first and they were able to pull footage from that episode to
This page is a part of DRG4's Marvel Cartoon Pages:
Featuring Spider-Man, X-Men, Fantastic Four, Iron Man, Incredible Hulk, and the Silver Surfer.